Stress Corrosion Cracking
Over the last several decades there has been a great deal
of conjecture and some studies reported in the literature concerning
the possibility for in vivo stress corrosion cracking of alloys
used for biomedical applications. Many of the reported incidences identifying
stress corrosion cracking as the mechanism of failure of retrieved
implants occurred before the 1970’s. Most of these reports
implicated 316L stainless steel while only a few ascribed this
failure mechanism to certain grades of CP titanium. Most of
the fundamental research studies were performed in saline solution
at 37ºC and some were also performed using more aggressive
media at elevated temperature. Because of a lack of definitive
correlation between these early reports, and because the composition
of implant quality 316L stainless steel has been redefined,
we embarked upon a program to assess the stress corrosion cracking
behavior of these materials under the same conditions. We have
begun by evaluating both the entire process to failure of the
three most commonly used stainless steels, CP titanium, two
a/ß titanium alloys, and a ß titanium alloy. All
of this research to date is in the literature or shortly will
be. We are continuing with this specific work to include all
of the alloys used for biomedical applications, as well as
expanding this area of research to include studies on the crack
propagation phase.